I had both systems but a much bigger Sony library and only had GoldenEye lol
I had both as well but I was a bigger Nintendo fan.
For PlayStation, I mostly had WWF games (Attitude, Warzone, and Smackdown) Soul Reaver, and Need For Speed until towards the end when I just started getting into JRPGS when I bought Chrono Cross. I got into the PS1 FF games and RPG Maker after playing FFX on the PS2. I actually first played FFVI, FFIV, and Chrono Trigger via their PS1 ports after playing FFVII-IX when I was really starting to get into the genre.
For N64, I had Super Mario 64, Yoshi’s Story, Mario Kart 64, Diddy Kong Racing, Banjo-Kazooie, Donkey Kong 64, GoldenEye, Perfect Dark, StarFox 64, F-Zero X, No Mercy, WCW vs NWO Revenge, Wrestlemania 2000, Ocarina of Time, Smash Bros., and Pokemon Stadium 1 and 2, Turok 2, Shadows of the Empire, Duke Nukem 64 and probably something else I’m forgetting right now.