Alright here's a list of attacks she does based on her boss fights:
1. Does a Farore’s Wind and (Sonic's) Spring-like style rocket jump, creates a small energy wave that hits you. She floats down afterwards.
2. Basic projectile shot, charges it above her head.
3. Shouts "Cover your eyes" and uses her staff to cover the screen in a blinding light.
4. Launches 3 pillars of light energy at you in a wave shot.
5. Holds her shield out and creates a single shield-like projectile that blocks most attacks.
6. Creates a giant pillar of light that covers her body and tries to slam into you.
7. Same as 2, just as a spread shot.
8. Summons a centurion.
9. In Chapter 3, she creates a giant beam of light that rains down from the sky. She calls it her "Palutena Glam Blaster," and later calls it the "Sacred Goddess Clobberlaser."
- These are from her imposter fight in Chapter 24:
10. Uses her shield similar to 5 to create two turrets that fire mini projectiles on you.
11. Machine guns mini projectiles at you, they also cause the poison status.
12. Launches forward and does a headbutt.
13. Similar to 2, but creates a large energy beam.
IMO:
N-Special: 2
U-Special: 1
S-Special: 8
D-Special: 5 or 6
Final Smash: 9
U-tilt or U-Air: 12
Definitely can see her as a defensive/projectile based character who's like a heavier Zelda without Sheik and the many weaker and less sweetspot based standards.