Espeon @ Leftovers
Magic Bounce
252 HP / 130 Def or Sp Def / 126 other defense (Just a personal Preference
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Bold/Calm
Substitute / Protect / Wish
Calm Mind
Baton Pass
Psychic / Psyshock / Wish
Magic Bounce keeps Taunt off Espeon and lets it setup with Calm Mind. Subs or Protect as Subs will take HP away from Espeon while Protect will let Espeon recover from damage though Subs can be passed through Baton Pass and protect Mismagius from entry..
Mismagius @ Focus Sash / Choice scarf / Leftovers
Levitate
252 Speed / 252 Sp atk / 4 HP, Def, or Sp Def
Timid / Modest (if Scarfed)
Shadow Ball
Thunderbolt / Thunder
Hidden Power (ice/Fire if Possible) / Energy Ball / Dazzling Gleam / Power Gem / Psychic
Will-o-Wisp / above move if Scarfed
Mismagius can use a choice scarf but it'll be restricted to one move. If you want to keep it's arsenal open for other pokemon you could give it a leftovers, or a Focus Sash for physical pokemon. though a scarf will come in handy in some situations where you need more speed to take down a threat usually another scarf user.. if you choose to not use a scarf then Will-o-Wisp is heavily recommended.
Zangoose @ Toxic Orb
Toxic Boost
252 Speed / 252 Atk / 4 HP, Def, or Sp Def
Adamant / Jolly
Facade
Protect / Swords Dance
Quick Attack
Night Slash
Protect or Swords dance first turn so the Toxic orb can poison Zangoose Facade does Double damage and with Toxic boost it'll deal even more damage. Quick attack for priority and Night Slash for ghost types.