The Unlockable Characters in the Vs. Match and Classic Mode orders/line-ups

[QuintonShark8714]

Vs. Matches Order/Line-up:

Spoiler

Ness
Zelda
Bowser
Pit
Inkling
Villager
Marth
Young Link
Wii Fit Trainer
Ice Climbers
Captain Falcon
Peach
Ryu
Ike
Jigglypuff
King K. Rool
Sonic
Simon
Zero Suit Samus
Little Mac
Isabelle
Shulk
Lucina
Wario
Ridley
Pokemon Trainer
Lucario
Daisy
Roy
King Dedede
R.O.B.
Falco
Luigi
Pichu
Lucas
Ricther
Diddy Kong
Meta Knight
Snake
Ganondorf
Corrin
Mega Man
Bayonetta
Toon Link
Rosalina & Luma
Incineroar
Shiek
Olimar
Pac-Man
Dark Samus
Wolf
Mr. Game & Watch
Robin
Dark Pit
Cloud
Duck Hunt
Ken
Greninja
Chrom
Mewtwo
Bowser Jr.
Dr. Mario
Palutena

Classic Mode Branches and Orders/Line-ups:

Spoiler

I hope all this helps

NOTE:
-if you already unlocked that character via Vs. Matches, the Classic Mode order/line-up will go straight to the next (EX; if you already unlocked Ness, you go straight to Jigglypuff, if you already unlocked Bowser via Vs. Matches, you go straight to Pokemon Trainer, so on and so fouth)
-You can also use any of the previous characters before the next in line regardless, (EX; you can either use all of them of that order/line-up, use the main one like let's say Fox, or Captain Falcon after you unlocked him)

Credits:
NeoSpartain from GameFAQs for the VS Match List
JoseR (@HiJoser) from Twitter for the Classic Mode order