Hard to say the definitive best single kill move, but here are some moves that are good for getting the kill for all of the characters. I think I got everyone, except for the Miis. Might have missed 1 or 2 characters
For
, its probably up tilt, or forward air. Its not super risky if spaced correctly, fair is super strong and good for edgeguarding., and can combo off of a bomb. Up smash is a good up smash but it isn't the most efficient way to get kills with Link, since its punishable and isn't a move that combos for a kill confirm. Good anti air though.
's most efficient kill move isn't Shieldbreaker. Forward smash of course, one of the best punish tools in the game. But I'd say its tipper fair or bair for edgeguards (since Marth excels at them and relys on them for some kills) onstage, I'd say up tilt or forward tilt, especially after a jab. Tipper Up air as well, off of the down throw 50/50, and Tipper nair, which is one of the strongest nairs in the game.
bair is incredibly powerful. Up air isn't as strong as it once was but still good. Raw raptor boost even.
- Up smash, bair, fair, up air, and up b. Even back throw. Mario has a lot of killpower
- Limit Cross Slash, Up air or spaced bair. Dash attack
- Fair, Bair, Up air, Dash attack has great range and power
- sweetspot aerials, or sweetspot up tilt, sometimes forward smash/up smash out of first hit nair.
- up smash because of down tilt --> up smash, fair, bair, occasionally up air
- Up air out of down throw, and bair.
- Forward Smash, its strong and has little lag. Shuttle Loop, Bair is surprisingly very powerful
- Dash attack and bair, since they both have invincibility. And up air of course.
- Up air, Boost Kick, Flip Kick, bair
- Vanish, Up air, bouncing fish
- Bair, Rest
- Dragon Lunge, Forward Smash with its insane range. Up air. Up air has massive range and one of the best aerials in the game.
- Up air, Bair, Up Smash since its fast and an extremely good punish tool. Confirms out of dair or reverse forward tilt too.
- Falco's bair is super strong. Up smash, fair for edgeguarding, and up air off the top.
- Up air from the ding dong, bair for edgeguarding and kills. Sweetspot up tilt is a good anti-air
- Nair, up air, smash attacks after Witch Time...
- Bair, Up air
- Bair, Fair, Forward Smash/Up smash
- Bair, up air, Force Palm has range with aura and is a kill when you command grab. Almost anything with aura really
- Up smash is a great anti-air and kill move, bair, Uppercut/Electroshock arms, and forward throw
- Up smash, down smash, bair
- True SHORYUKEN
- Luma up air...
- Up air, bair, forward smash, up smash
- up throw, up air, down air
- Up throw is arguably the best up throw in the game, although
's is more commonly seen. Bair is ridiculously strong, up air, flare blitz occasionally
- Up throw, one of the best and consistent kill throws, Fair, bair
- Up b, forward smash, fair out of down throw or as a punish
- Smash attacks, up air
- Up b, side b, smash attacks
- up smash, Up b Shoryuken, bair, nair
- Forward Smash/Up Smash
- Screw Attack, Forward Smash, Bair, Nair is hella strong
- Up smash? Bair, side b. Don't really know
- Crown Smack Forward Air, Forward Throw, Up smash
- Up throw, forward air sweetspot, up air
- Up air, forward tilt, Dair, bair, Flame Choke offstage if that counts
- Bair, up air, a shoryuken up tilt
- up air, Farore's Wind Up B
- Fair, Up smash, up air
- Smash Monado up tilt, Jump monado Up air, forward smash, fair/bair for edgeguards and kills
- that damn forward smash, up air off the top, bair is strong
- Thunder, Up smash, forward smash
- Up smash, up air, back throw, forward air
- Bowling Ball, Three turnip up air, up smash, up tilt
- Hydrant setups, up smash with the bell thing that paralyzes. And the key. Also Side b
- Toot toot up air, Up smash, and fair
- Up air, Forward Air
- Purple Pikmin aerials..? Forward smash
- Wario Waft, bair
- Back Throw, big head up air, bair, forward smash, and down smash to punish people on the ledge.